(3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions

Piotr Stefanowicz; Mariusz Jaremko; Łukasz Jaremko; Andrzej Kochel

doi:10.1107/S0108270107006646

(3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions

Piotr Stefanowicz
, Mariusz Jaremko
, Łukasz Jaremko
, Andrzej Kochel

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, C10H12O5N2, crystallizes with two independent mol-ecules in the asymmetric unit. The mol-ecules in the crystal structure are arranged into one-dimensional substructural ribbon motifs stabilized by a combination of two O - H⋯O and three N - H⋯O inter-molecular hydrogen bonds, and also augmented by short C=O⋯C=O carbon-yl-carbonyl inter-actions. Two inter-molecular C - H⋯O short contacts between adjacent ribbons generate complex two-dimensional sheets on the ab plane. Adjacent sheets are linked via C - H⋯π(arene) inter-actions, resulting in a complex three-dimensional framework.

Original language	English (US)
Pages (from-to)	o204-o206
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	63
Issue number	3
DOIs	https://doi.org/10.1107/S0108270107006646
State	Published - Feb 10 2007
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

Access to Document

10.1107/S0108270107006646

Fingerprint

Dive into the research topics of '(3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions'. Together they form a unique fingerprint.

Cite this

Stefanowicz, P., Jaremko, M., Jaremko, Ł., & Kochel, A. (2007). (3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions. Acta Crystallographica Section C: Crystal Structure Communications, 63(3), o204-o206. https://doi.org/10.1107/S0108270107006646

(3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions. / Stefanowicz, Piotr; Jaremko, Mariusz; Jaremko, Łukasz et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 63, No. 3, 10.02.2007, p. o204-o206.

Research output: Contribution to journal › Article › peer-review

Stefanowicz, P, Jaremko, M, Jaremko, Ł & Kochel, A 2007, '(3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions', Acta Crystallographica Section C: Crystal Structure Communications, vol. 63, no. 3, pp. o204-o206. https://doi.org/10.1107/S0108270107006646

Stefanowicz P, Jaremko M, Jaremko Ł, Kochel A. (3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions. Acta Crystallographica Section C: Crystal Structure Communications. 2007 Feb 10;63(3):o204-o206. doi: 10.1107/S0108270107006646

Stefanowicz, Piotr ; Jaremko, Mariusz ; Jaremko, Łukasz et al. / (3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate : Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions. In: Acta Crystallographica Section C: Crystal Structure Communications. 2007 ; Vol. 63, No. 3. pp. o204-o206.

@article{7cbebf34c3e14472aecc50e76d436726,

title = "(3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions",

abstract = "The title compound, C10H12O5N2, crystallizes with two independent mol-ecules in the asymmetric unit. The mol-ecules in the crystal structure are arranged into one-dimensional substructural ribbon motifs stabilized by a combination of two O - H⋯O and three N - H⋯O inter-molecular hydrogen bonds, and also augmented by short C=O⋯C=O carbon-yl-carbonyl inter-actions. Two inter-molecular C - H⋯O short contacts between adjacent ribbons generate complex two-dimensional sheets on the ab plane. Adjacent sheets are linked via C - H⋯π(arene) inter-actions, resulting in a complex three-dimensional framework.",

author = "Piotr Stefanowicz and Mariusz Jaremko and {\L}ukasz Jaremko and Andrzej Kochel",

year = "2007",

month = feb,

day = "10",

doi = "10.1107/S0108270107006646",

language = "English (US)",

volume = "63",

pages = "o204--o206",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - (3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate

T2 - Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions

AU - Stefanowicz, Piotr

AU - Jaremko, Mariusz

AU - Jaremko, Łukasz

AU - Kochel, Andrzej

PY - 2007/2/10

Y1 - 2007/2/10

N2 - The title compound, C10H12O5N2, crystallizes with two independent mol-ecules in the asymmetric unit. The mol-ecules in the crystal structure are arranged into one-dimensional substructural ribbon motifs stabilized by a combination of two O - H⋯O and three N - H⋯O inter-molecular hydrogen bonds, and also augmented by short C=O⋯C=O carbon-yl-carbonyl inter-actions. Two inter-molecular C - H⋯O short contacts between adjacent ribbons generate complex two-dimensional sheets on the ab plane. Adjacent sheets are linked via C - H⋯π(arene) inter-actions, resulting in a complex three-dimensional framework.

AB - The title compound, C10H12O5N2, crystallizes with two independent mol-ecules in the asymmetric unit. The mol-ecules in the crystal structure are arranged into one-dimensional substructural ribbon motifs stabilized by a combination of two O - H⋯O and three N - H⋯O inter-molecular hydrogen bonds, and also augmented by short C=O⋯C=O carbon-yl-carbonyl inter-actions. Two inter-molecular C - H⋯O short contacts between adjacent ribbons generate complex two-dimensional sheets on the ab plane. Adjacent sheets are linked via C - H⋯π(arene) inter-actions, resulting in a complex three-dimensional framework.

UR - https://www.scopus.com/pages/publications/33847710369

UR - https://www.scopus.com/pages/publications/33847710369#tab=citedBy

U2 - 10.1107/S0108270107006646

DO - 10.1107/S0108270107006646

M3 - Article

AN - SCOPUS:33847710369

SN - 0108-2701

VL - 63

SP - o204-o206

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 3

ER -

(3S)-Benzyl N-(1-hydr-oxy-2,5-dioxopyrrolidin-3-yl)carbamate: Two-dimensional sheets built from O - H⋯O, N - H⋯d c - ⋯hO inter-acti⋯ons linked into a three-dimensional complex framework via C - H(arene) inte⋯πr-actions

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this