Calculation of temperature-dependent multimode resonance Raman line shapes for harmonic potential surfaces

Richard Friesner, Bernard Pettitt, John M. Jean

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

An exact form for the time dependent resonance Raman kernel at finite temperature is derived under the assumption that the ground and excited state potential surfaces of the system are harmonic. The resultant expression can be evaluated by matrix algebra and Fourier transformed numerically to recover Raman scattering and excitation profiles.

Original languageEnglish (US)
Pages (from-to)2918-2926
Number of pages9
JournalThe Journal of Chemical Physics
Volume82
Issue number7
StatePublished - 1984
Externally publishedYes

Fingerprint

Excited states
Ground state
line shape
Raman scattering
harmonics
excitation
algebra
Raman spectra
Temperature
ground state
temperature
profiles

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Calculation of temperature-dependent multimode resonance Raman line shapes for harmonic potential surfaces. / Friesner, Richard; Pettitt, Bernard; Jean, John M.

In: The Journal of Chemical Physics, Vol. 82, No. 7, 1984, p. 2918-2926.

Research output: Contribution to journalArticle

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