TY - JOUR
T1 - Chaotic motion in bending induced intramolecular transition
T2 - A case study of HCN, HNC and the transition state
AU - Ou, Shuching
AU - Wu, Guozhen
AU - Wang, Peijie
N1 - Funding Information:
This is supported by a fund from the National Natural Science Foundation of China (Grant No. 20373030).
PY - 2006/12/11
Y1 - 2006/12/11
N2 - Chaotic motion in the bending induced intramolecular transition of HCN, HNC and the transition state is explored by three approaches: (1) Lyapunov analysis, which is based on the classical phase space for the levels, (2) statistical analysis of the distribution of the adjacent level spacing and (3) analysis based on level spacing dips, which integrates the concepts of pendulum dynamics and quantized levels. The three analyses show consistent conclusions: chaos appears only above the transition point and the degree of chaos shows fluctuations as the level energy increases.
AB - Chaotic motion in the bending induced intramolecular transition of HCN, HNC and the transition state is explored by three approaches: (1) Lyapunov analysis, which is based on the classical phase space for the levels, (2) statistical analysis of the distribution of the adjacent level spacing and (3) analysis based on level spacing dips, which integrates the concepts of pendulum dynamics and quantized levels. The three analyses show consistent conclusions: chaos appears only above the transition point and the degree of chaos shows fluctuations as the level energy increases.
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U2 - 10.1016/j.cplett.2006.10.122
DO - 10.1016/j.cplett.2006.10.122
M3 - Article
AN - SCOPUS:37849185284
VL - 432
SP - 623
EP - 628
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 4-6
ER -