DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism

Ye Ding, Zhangjian Huang, Jian Yin, Yisheng Lai, Shibo Zhang, Zhiguo Zhang, Lei Fang, Sixun Peng, Yihua Zhang

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A novel and facile DDQ-mediated dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones is described. The formation of lactones proceeds by a radical ion mechanism, which has been established by DPPH -mediated chemical identification, ESR spectroscopy and an enol intermediate trapping.

Original languageEnglish (US)
Pages (from-to)9495-9497
Number of pages3
JournalChemical Communications
Volume47
Issue number33
DOIs
StatePublished - Sep 7 2011
Externally publishedYes

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Lactones
Dehydrogenation
Ions
Acids
Paramagnetic resonance
Spectroscopy

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism. / Ding, Ye; Huang, Zhangjian; Yin, Jian; Lai, Yisheng; Zhang, Shibo; Zhang, Zhiguo; Fang, Lei; Peng, Sixun; Zhang, Yihua.

In: Chemical Communications, Vol. 47, No. 33, 07.09.2011, p. 9495-9497.

Research output: Contribution to journalArticle

Ding, Ye ; Huang, Zhangjian ; Yin, Jian ; Lai, Yisheng ; Zhang, Shibo ; Zhang, Zhiguo ; Fang, Lei ; Peng, Sixun ; Zhang, Yihua. / DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism. In: Chemical Communications. 2011 ; Vol. 47, No. 33. pp. 9495-9497.
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