DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism

Ye Ding; Zhangjian Huang; Jian Yin; Yisheng Lai; Shibo Zhang; Zhiguo Zhang; Lei Fang; Sixun Peng; Yihua Zhang

doi:10.1039/c1cc11633a

DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism

Ye Ding
, Zhangjian Huang
, Jian Yin
, Yisheng Lai
, Shibo Zhang
, Zhiguo Zhang
, Lei Fang
, Sixun Peng
, Yihua Zhang

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A novel and facile DDQ-mediated dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones is described. The formation of lactones proceeds by a radical ion mechanism, which has been established by DPPH^•-mediated chemical identification, ESR spectroscopy and an enol intermediate trapping.

Original language	English (US)
Pages (from-to)	9495-9497
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	33
DOIs	https://doi.org/10.1039/c1cc11633a
State	Published - Sep 7 2011
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc11633a

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title = "DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism",

abstract = "A novel and facile DDQ-mediated dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones is described. The formation of lactones proceeds by a radical ion mechanism, which has been established by DPPH•-mediated chemical identification, ESR spectroscopy and an enol intermediate trapping.",

author = "Ye Ding and Zhangjian Huang and Jian Yin and Yisheng Lai and Shibo Zhang and Zhiguo Zhang and Lei Fang and Sixun Peng and Yihua Zhang",

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T1 - DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism

AU - Ding, Ye

AU - Huang, Zhangjian

AU - Yin, Jian

AU - Lai, Yisheng

AU - Zhang, Shibo

AU - Zhang, Zhiguo

AU - Fang, Lei

AU - Peng, Sixun

AU - Zhang, Yihua

PY - 2011/9/7

Y1 - 2011/9/7

N2 - A novel and facile DDQ-mediated dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones is described. The formation of lactones proceeds by a radical ion mechanism, which has been established by DPPH•-mediated chemical identification, ESR spectroscopy and an enol intermediate trapping.

AB - A novel and facile DDQ-mediated dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones is described. The formation of lactones proceeds by a radical ion mechanism, which has been established by DPPH•-mediated chemical identification, ESR spectroscopy and an enol intermediate trapping.

UR - https://www.scopus.com/pages/publications/80051581541

UR - https://www.scopus.com/pages/publications/80051581541#tab=citedBy

U2 - 10.1039/c1cc11633a

DO - 10.1039/c1cc11633a

M3 - Article

C2 - 21766102

AN - SCOPUS:80051581541

SN - 1359-7345

VL - 47

SP - 9495

EP - 9497

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism

Abstract

ASJC Scopus subject areas

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