Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand

Łukasz Jaremko; Alexander M. Kirillov; Piotr Smoleński; Tadeusz Lis; Armando J.L. Pombeiro

doi:10.1021/ic702373b

Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand

Łukasz Jaremko
, Alexander M. Kirillov
, Piotr Smoleński
, Tadeusz Lis
, Armando J.L. Pombeiro

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Water-soluble Co^III and Co^II complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.

Original language	English (US)
Pages (from-to)	2922-2924
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	8
DOIs	https://doi.org/10.1021/ic702373b
State	Published - Apr 21 2008
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic702373b

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Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand. / Jaremko, Łukasz; Kirillov, Alexander M.; Smoleński, Piotr et al.
In: Inorganic Chemistry, Vol. 47, No. 8, 21.04.2008, p. 2922-2924.

Research output: Contribution to journal › Article › peer-review

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abstract = "Water-soluble CoIII and CoII complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.",

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AU - Smoleński, Piotr

AU - Lis, Tadeusz

AU - Pombeiro, Armando J.L.

PY - 2008/4/21

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AB - Water-soluble CoIII and CoII complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.

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Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand

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