Gelation of siloxane cross-linked organic molecules

A. Vainrub, F. Devreux, M. Sarkar, P. D. Palasz, A. N. Burgess

    Research output: Contribution to journalArticle

    1 Scopus citations

    Abstract

    We have studied by 29Si NMR and small angle neutron scattering the cross-linking by formation of siloxane bridges of two amino-epoxy-silane molecules at different concentration in acidic water. We relate our observations to the fact that one of the studied systems never gels, while the second one displays a concentration threshold for gelation that is accounted for by percolation theory.

    Original languageEnglish (US)
    Pages (from-to)279-285
    Number of pages7
    JournalJournal of Sol-Gel Science and Technology
    Volume6
    Issue number3
    DOIs
    StatePublished - Jan 1 1996

    Keywords

    • Gelation
    • NMR
    • SANS
    • Siloxane cross-linking
    • Sol-gel process

    ASJC Scopus subject areas

    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Biomaterials
    • Condensed Matter Physics
    • Materials Chemistry

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  • Cite this

    Vainrub, A., Devreux, F., Sarkar, M., Palasz, P. D., & Burgess, A. N. (1996). Gelation of siloxane cross-linked organic molecules. Journal of Sol-Gel Science and Technology, 6(3), 279-285. https://doi.org/10.1007/BF00402700