Gelation of siloxane cross-linked organic molecules

A. Vainrub; F. Devreux; M. Sarkar; P. D. Palasz; A. N. Burgess

doi:10.1007/BF00402700

Gelation of siloxane cross-linked organic molecules

A. Vainrub, F. Devreux, M. Sarkar, P. D. Palasz, A. N. Burgess

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

We have studied by ²⁹Si NMR and small angle neutron scattering the cross-linking by formation of siloxane bridges of two amino-epoxy-silane molecules at different concentration in acidic water. We relate our observations to the fact that one of the studied systems never gels, while the second one displays a concentration threshold for gelation that is accounted for by percolation theory.

Original language	English (US)
Pages (from-to)	279-285
Number of pages	7
Journal	Journal of Sol-Gel Science and Technology
Volume	6
Issue number	3
DOIs	https://doi.org/10.1007/BF00402700
State	Published - 1996
Externally published	Yes

Keywords

Gelation
NMR
SANS
Siloxane cross-linking
Sol-gel process

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Biomaterials
Condensed Matter Physics
Materials Chemistry

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10.1007/BF00402700

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title = "Gelation of siloxane cross-linked organic molecules",

abstract = "We have studied by 29Si NMR and small angle neutron scattering the cross-linking by formation of siloxane bridges of two amino-epoxy-silane molecules at different concentration in acidic water. We relate our observations to the fact that one of the studied systems never gels, while the second one displays a concentration threshold for gelation that is accounted for by percolation theory.",

keywords = "Gelation, NMR, SANS, Siloxane cross-linking, Sol-gel process",

author = "A. Vainrub and F. Devreux and M. Sarkar and Palasz, {P. D.} and Burgess, {A. N.}",

year = "1996",

doi = "10.1007/BF00402700",

language = "English (US)",

volume = "6",

pages = "279--285",

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T1 - Gelation of siloxane cross-linked organic molecules

AU - Vainrub, A.

AU - Devreux, F.

AU - Sarkar, M.

AU - Palasz, P. D.

AU - Burgess, A. N.

PY - 1996

Y1 - 1996

N2 - We have studied by 29Si NMR and small angle neutron scattering the cross-linking by formation of siloxane bridges of two amino-epoxy-silane molecules at different concentration in acidic water. We relate our observations to the fact that one of the studied systems never gels, while the second one displays a concentration threshold for gelation that is accounted for by percolation theory.

AB - We have studied by 29Si NMR and small angle neutron scattering the cross-linking by formation of siloxane bridges of two amino-epoxy-silane molecules at different concentration in acidic water. We relate our observations to the fact that one of the studied systems never gels, while the second one displays a concentration threshold for gelation that is accounted for by percolation theory.

KW - Gelation

KW - NMR

KW - SANS

KW - Siloxane cross-linking

KW - Sol-gel process

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U2 - 10.1007/BF00402700

DO - 10.1007/BF00402700

M3 - Article

AN - SCOPUS:0029709606

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JO - Journal of Sol-Gel Science and Technology

JF - Journal of Sol-Gel Science and Technology

IS - 3

ER -

Gelation of siloxane cross-linked organic molecules

Abstract

Keywords

ASJC Scopus subject areas

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