Heterocyclizations of 1-(Benzothiazol-2-yl)-4-phenylthiosemicarbazide

P. V. Savitskii, R. I. Vas'Kevich, Yu L. Zborovskii, V. I. Staninets, Sergii Buth, A. N. Chernega

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

1-(Benzothiazol-2-yl)-4-phenylthiosemicarbazide reacted with methyl iodide in the presence of sodium acetate in boiling ethanol to give 2,2′-dithiobis[N-(5-methylsulfanyl-4-phenyl-4H-1,2,4-triazol-3-yl) -benzenamine]. The reaction of the title compound with dimethyl acetylenedicarboxylate in dioxane led to the formation of methyl 3-(benzothiazol-2-yl)-2-(2-methoxy-2-oxoethyl)-2,3-dihydro-1,3, 4-thiadiazole-2-carboxylate.

Original languageEnglish (US)
Pages (from-to)402-406
Number of pages5
JournalRussian Journal of Organic Chemistry
Volume44
Issue number3
DOIs
StatePublished - Mar 2008
Externally publishedYes

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Sodium Acetate
Boiling liquids
Ethanol
acetylenedicarboxylic acid dimethyl ester
aniline
1,4-dioxane
1,3,4-thiadiazole
methyl iodide

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Savitskii, P. V., Vas'Kevich, R. I., Zborovskii, Y. L., Staninets, V. I., Buth, S., & Chernega, A. N. (2008). Heterocyclizations of 1-(Benzothiazol-2-yl)-4-phenylthiosemicarbazide. Russian Journal of Organic Chemistry, 44(3), 402-406. https://doi.org/10.1007/s11178-008-3015-2

Heterocyclizations of 1-(Benzothiazol-2-yl)-4-phenylthiosemicarbazide. / Savitskii, P. V.; Vas'Kevich, R. I.; Zborovskii, Yu L.; Staninets, V. I.; Buth, Sergii; Chernega, A. N.

In: Russian Journal of Organic Chemistry, Vol. 44, No. 3, 03.2008, p. 402-406.

Research output: Contribution to journalArticle

Savitskii, PV, Vas'Kevich, RI, Zborovskii, YL, Staninets, VI, Buth, S & Chernega, AN 2008, 'Heterocyclizations of 1-(Benzothiazol-2-yl)-4-phenylthiosemicarbazide', Russian Journal of Organic Chemistry, vol. 44, no. 3, pp. 402-406. https://doi.org/10.1007/s11178-008-3015-2
Savitskii PV, Vas'Kevich RI, Zborovskii YL, Staninets VI, Buth S, Chernega AN. Heterocyclizations of 1-(Benzothiazol-2-yl)-4-phenylthiosemicarbazide. Russian Journal of Organic Chemistry. 2008 Mar;44(3):402-406. https://doi.org/10.1007/s11178-008-3015-2
Savitskii, P. V. ; Vas'Kevich, R. I. ; Zborovskii, Yu L. ; Staninets, V. I. ; Buth, Sergii ; Chernega, A. N. / Heterocyclizations of 1-(Benzothiazol-2-yl)-4-phenylthiosemicarbazide. In: Russian Journal of Organic Chemistry. 2008 ; Vol. 44, No. 3. pp. 402-406.
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