N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent

Synthesis and analytical application

Netkal M. Made Gowda, V-M Ramanujam, Norman M. Trieff, G. John Stanton, Dandinasivara S. Mahadevappa

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A new oxidimetric reagent, dichloramine-N (N,N′-dichloro-p-nitrobenzenesulfonamide; DCN) has been synthesized and its structure elucidated from the spectral data and elemental analyses. The ultraviolet, infrared, nuclear magnetic resonance, and mass spectral data have been presented. Analytical applications of DCN as a potential redox titrant in the determination of diverse reductants such as ascorbic acid, methionine, sulfite, arsenite, glutathione, and indigocarmine have been described.

Original languageEnglish (US)
Pages (from-to)95-104
Number of pages10
JournalMicrochemical Journal
Volume26
Issue number1
DOIs
StatePublished - 1981

Fingerprint

Sulfites
Reducing Agents
Methionine
Ascorbic Acid
Glutathione
Nuclear magnetic resonance
Infrared radiation
arsenite
Oxidation-Reduction

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent : Synthesis and analytical application. / Made Gowda, Netkal M.; Ramanujam, V-M; Trieff, Norman M.; Stanton, G. John; Mahadevappa, Dandinasivara S.

In: Microchemical Journal, Vol. 26, No. 1, 1981, p. 95-104.

Research output: Contribution to journalArticle

Made Gowda, Netkal M. ; Ramanujam, V-M ; Trieff, Norman M. ; Stanton, G. John ; Mahadevappa, Dandinasivara S. / N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent : Synthesis and analytical application. In: Microchemical Journal. 1981 ; Vol. 26, No. 1. pp. 95-104.
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