N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent: Synthesis and analytical application

Netkal M. Made Gowda; V. M.Sadagopa Ramanujam; Norman M. Trieff; G. John Stanton; Dandinasivara S. Mahadevappa

doi:10.1016/0026-265X(81)90015-1

N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent: Synthesis and analytical application

Netkal M. Made Gowda
, V. M.Sadagopa Ramanujam
, Norman M. Trieff
, G. John Stanton
, Dandinasivara S. Mahadevappa

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new oxidimetric reagent, dichloramine-N (N,N′-dichloro-p-nitrobenzenesulfonamide; DCN) has been synthesized and its structure elucidated from the spectral data and elemental analyses. The ultraviolet, infrared, nuclear magnetic resonance, and mass spectral data have been presented. Analytical applications of DCN as a potential redox titrant in the determination of diverse reductants such as ascorbic acid, methionine, sulfite, arsenite, glutathione, and indigocarmine have been described.

Original language	English (US)
Pages (from-to)	95-104
Number of pages	10
Journal	Microchemical Journal
Volume	26
Issue number	1
DOIs	https://doi.org/10.1016/0026-265X(81)90015-1
State	Published - Mar 1981
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Spectroscopy

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10.1016/0026-265X(81)90015-1

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@article{a6063a8bf3fd4c4b8cf6b062b29a4b0e,

title = "N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent: Synthesis and analytical application",

abstract = "A new oxidimetric reagent, dichloramine-N (N,N′-dichloro-p-nitrobenzenesulfonamide; DCN) has been synthesized and its structure elucidated from the spectral data and elemental analyses. The ultraviolet, infrared, nuclear magnetic resonance, and mass spectral data have been presented. Analytical applications of DCN as a potential redox titrant in the determination of diverse reductants such as ascorbic acid, methionine, sulfite, arsenite, glutathione, and indigocarmine have been described.",

author = "\{Made Gowda\}, \{Netkal M.\} and Ramanujam, \{V. M.Sadagopa\} and Trieff, \{Norman M.\} and Stanton, \{G. John\} and Mahadevappa, \{Dandinasivara S.\}",

note = "Funding Information: This study was supportedb y the James W. McLaughlin Fellowship Fund (Grant to Drs. NMT, GJS, and NMMG) and the Robert A. Welch Foundation( Grant H-416t o Dr. NMT). The authorsa lso thank Dr. D. J. Leggett, Departmento f Chemistry, University of Houston, Texas for the {\textquoteleft}H and 13CN MR spectra.",

year = "1981",

month = mar,

doi = "10.1016/0026-265X(81)90015-1",

language = "English (US)",

volume = "26",

pages = "95--104",

journal = "Microchemical Journal",

issn = "0026-265X",

publisher = "Elsevier Inc.",

number = "1",

}

TY - JOUR

T1 - N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent

T2 - Synthesis and analytical application

AU - Made Gowda, Netkal M.

AU - Ramanujam, V. M.Sadagopa

AU - Trieff, Norman M.

AU - Stanton, G. John

AU - Mahadevappa, Dandinasivara S.

N1 - Funding Information: This study was supportedb y the James W. McLaughlin Fellowship Fund (Grant to Drs. NMT, GJS, and NMMG) and the Robert A. Welch Foundation( Grant H-416t o Dr. NMT). The authorsa lso thank Dr. D. J. Leggett, Departmento f Chemistry, University of Houston, Texas for the ‘H and 13CN MR spectra.

PY - 1981/3

Y1 - 1981/3

N2 - A new oxidimetric reagent, dichloramine-N (N,N′-dichloro-p-nitrobenzenesulfonamide; DCN) has been synthesized and its structure elucidated from the spectral data and elemental analyses. The ultraviolet, infrared, nuclear magnetic resonance, and mass spectral data have been presented. Analytical applications of DCN as a potential redox titrant in the determination of diverse reductants such as ascorbic acid, methionine, sulfite, arsenite, glutathione, and indigocarmine have been described.

AB - A new oxidimetric reagent, dichloramine-N (N,N′-dichloro-p-nitrobenzenesulfonamide; DCN) has been synthesized and its structure elucidated from the spectral data and elemental analyses. The ultraviolet, infrared, nuclear magnetic resonance, and mass spectral data have been presented. Analytical applications of DCN as a potential redox titrant in the determination of diverse reductants such as ascorbic acid, methionine, sulfite, arsenite, glutathione, and indigocarmine have been described.

UR - https://www.scopus.com/pages/publications/0347872268

UR - https://www.scopus.com/pages/publications/0347872268#tab=citedBy

U2 - 10.1016/0026-265X(81)90015-1

DO - 10.1016/0026-265X(81)90015-1

M3 - Article

AN - SCOPUS:0347872268

SN - 0026-265X

VL - 26

SP - 95

EP - 104

JO - Microchemical Journal

JF - Microchemical Journal

IS - 1

ER -

N,N′-dichloro-p-nitrobenzenesulfonamide (dichloramine-N) as a new oxidimetric reagent: Synthesis and analytical application

Abstract

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