Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand

Daniela Belli Dell'Amico, Fausto Calderazzo, Luca Labella, Fabio Marchetti, Elena Sbrana

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

By using [RuCl24-COD)]n, COD=cycloocta-1,5-diene (C8H12) or [RuCl26-cym)]2, cym = p-methyl-isopropylbenzene, as precursors, N,N-dialkylcarbamato complexes of ruthenium(II) containing the unsaturated hydrocarbon as ligand have been prepared, namely Ru(O2CNEt2)26-cym), 6, are reported. Compound 6, which represents the first example of a crystallographically established compound with the η6-arene-O2 CNR2 ligand combination, contains both monodentate and bidentate carbamato ligands. The reaction and structural patterns appear to conform systematically to the 18-electron rule for organometallic derivatives.

Original languageEnglish (US)
Pages (from-to)52-59
Number of pages8
JournalJournal of Organometallic Chemistry
Volume651
Issue number1-2
DOIs
StatePublished - May 15 2002

Keywords

  • N,N-dialkylacarbamato
  • Organometallic complex
  • Ruthenium(II)

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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