Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand

Daniela Belli Dell'Amico; Fausto Calderazzo; Luca Labella; Fabio Marchetti; Elena Sbrana

doi:10.1016/S0022-328X(02)01222-6

Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand

Daniela Belli Dell'Amico, Fausto Calderazzo, Luca Labella, Fabio Marchetti, Elena Sbrana

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Abstract

By using [RuCl₂(η⁴-COD)]_n, COD=cycloocta-1,5-diene (C₈H₁₂) or [RuCl₂(η⁶-cym)]₂, cym = p-methyl-isopropylbenzene, as precursors, N,N-dialkylcarbamato complexes of ruthenium(II) containing the unsaturated hydrocarbon as ligand have been prepared, namely Ru(O₂CNEt₂)₂(η⁶-cym), 6, are reported. Compound 6, which represents the first example of a crystallographically established compound with the η⁶-arene-O₂ CNR₂ ligand combination, contains both monodentate and bidentate carbamato ligands. The reaction and structural patterns appear to conform systematically to the 18-electron rule for organometallic derivatives.

Original language	English (US)
Pages (from-to)	52-59
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	651
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(02)01222-6
State	Published - May 15 2002

Keywords

N,N-dialkylacarbamato
Organometallic complex
Ruthenium(II)

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(02)01222-6

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title = "Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand",

abstract = "By using [RuCl2(η4-COD)]n, COD=cycloocta-1,5-diene (C8H12) or [RuCl2(η6-cym)]2, cym = p-methyl-isopropylbenzene, as precursors, N,N-dialkylcarbamato complexes of ruthenium(II) containing the unsaturated hydrocarbon as ligand have been prepared, namely Ru(O2CNEt2)2(η6-cym), 6, are reported. Compound 6, which represents the first example of a crystallographically established compound with the η6-arene-O2 CNR2 ligand combination, contains both monodentate and bidentate carbamato ligands. The reaction and structural patterns appear to conform systematically to the 18-electron rule for organometallic derivatives.",

keywords = "N,N-dialkylacarbamato, Organometallic complex, Ruthenium(II)",

author = "{Belli Dell'Amico}, Daniela and Fausto Calderazzo and Luca Labella and Fabio Marchetti and Elena Sbrana",

note = "Funding Information: The authors wish to thank the Ministero dell{\textquoteright} Universit{\`a} e della Ricerca Scientifica e Tecnologica (MURST), Programmi di Rilevante Interesse Nazionale 2000-1, for financial support and the COST Action D17/003 of the European Community for promoting scientific activity.",

year = "2002",

month = may,

day = "15",

doi = "10.1016/S0022-328X(02)01222-6",

language = "English (US)",

volume = "651",

pages = "52--59",

journal = "Journal of Organometallic Chemistry",

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T1 - Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand

AU - Belli Dell'Amico, Daniela

AU - Calderazzo, Fausto

AU - Labella, Luca

AU - Marchetti, Fabio

AU - Sbrana, Elena

N1 - Funding Information: The authors wish to thank the Ministero dell’ Università e della Ricerca Scientifica e Tecnologica (MURST), Programmi di Rilevante Interesse Nazionale 2000-1, for financial support and the COST Action D17/003 of the European Community for promoting scientific activity.

PY - 2002/5/15

Y1 - 2002/5/15

N2 - By using [RuCl2(η4-COD)]n, COD=cycloocta-1,5-diene (C8H12) or [RuCl2(η6-cym)]2, cym = p-methyl-isopropylbenzene, as precursors, N,N-dialkylcarbamato complexes of ruthenium(II) containing the unsaturated hydrocarbon as ligand have been prepared, namely Ru(O2CNEt2)2(η6-cym), 6, are reported. Compound 6, which represents the first example of a crystallographically established compound with the η6-arene-O2 CNR2 ligand combination, contains both monodentate and bidentate carbamato ligands. The reaction and structural patterns appear to conform systematically to the 18-electron rule for organometallic derivatives.

AB - By using [RuCl2(η4-COD)]n, COD=cycloocta-1,5-diene (C8H12) or [RuCl2(η6-cym)]2, cym = p-methyl-isopropylbenzene, as precursors, N,N-dialkylcarbamato complexes of ruthenium(II) containing the unsaturated hydrocarbon as ligand have been prepared, namely Ru(O2CNEt2)2(η6-cym), 6, are reported. Compound 6, which represents the first example of a crystallographically established compound with the η6-arene-O2 CNR2 ligand combination, contains both monodentate and bidentate carbamato ligands. The reaction and structural patterns appear to conform systematically to the 18-electron rule for organometallic derivatives.

KW - N,N-dialkylacarbamato

KW - Organometallic complex

KW - Ruthenium(II)

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DO - 10.1016/S0022-328X(02)01222-6

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SN - 0022-328X

VL - 651

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EP - 59

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand

Abstract

Keywords

ASJC Scopus subject areas

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