Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand

Daniela Belli Dell'Amico, Fausto Calderazzo, Luca Labella, Fabio Marchetti, Elena Sbrana

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

By using [RuCl24-COD)]n, COD=cycloocta-1,5-diene (C8H12) or [RuCl26-cym)]2, cym = p-methyl-isopropylbenzene, as precursors, N,N-dialkylcarbamato complexes of ruthenium(II) containing the unsaturated hydrocarbon as ligand have been prepared, namely Ru(O2CNEt2)26-cym), 6, are reported. Compound 6, which represents the first example of a crystallographically established compound with the η6-arene-O2 CNR2 ligand combination, contains both monodentate and bidentate carbamato ligands. The reaction and structural patterns appear to conform systematically to the 18-electron rule for organometallic derivatives.

Original languageEnglish (US)
Pages (from-to)52-59
Number of pages8
JournalJournal of Organometallic Chemistry
Volume651
Issue number1-2
DOIs
StatePublished - May 15 2002
Externally publishedYes

Fingerprint

Ruthenium
Organometallics
ruthenium
crack opening displacement
Ligands
ligands
dienes
Hydrocarbons
hydrocarbons
Electrons
Derivatives
electrons

Keywords

  • N,N-dialkylacarbamato
  • Organometallic complex
  • Ruthenium(II)

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand. / Belli Dell'Amico, Daniela; Calderazzo, Fausto; Labella, Luca; Marchetti, Fabio; Sbrana, Elena.

In: Journal of Organometallic Chemistry, Vol. 651, No. 1-2, 15.05.2002, p. 52-59.

Research output: Contribution to journalArticle

Belli Dell'Amico, D, Calderazzo, F, Labella, L, Marchetti, F & Sbrana, E 2002, 'Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand', Journal of Organometallic Chemistry, vol. 651, no. 1-2, pp. 52-59. https://doi.org/10.1016/S0022-328X(02)01222-6
Belli Dell'Amico, Daniela ; Calderazzo, Fausto ; Labella, Luca ; Marchetti, Fabio ; Sbrana, Elena. / Organometallic complexes of ruthenium(II) with N,N-dialkylcarbamato as the supporting ligand. In: Journal of Organometallic Chemistry. 2002 ; Vol. 651, No. 1-2. pp. 52-59.
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abstract = "By using [RuCl2(η4-COD)]n, COD=cycloocta-1,5-diene (C8H12) or [RuCl2(η6-cym)]2, cym = p-methyl-isopropylbenzene, as precursors, N,N-dialkylcarbamato complexes of ruthenium(II) containing the unsaturated hydrocarbon as ligand have been prepared, namely Ru(O2CNEt2)2(η6-cym), 6, are reported. Compound 6, which represents the first example of a crystallographically established compound with the η6-arene-O2 CNR2 ligand combination, contains both monodentate and bidentate carbamato ligands. The reaction and structural patterns appear to conform systematically to the 18-electron rule for organometallic derivatives.",
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AU - Calderazzo, Fausto

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AU - Marchetti, Fabio

AU - Sbrana, Elena

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