Selective incorporation of 5-hydroxytryptophan blocks long range electron transfer in oxalate decarboxylase

Keyphrases

• 5-Hydroxytryptophan (5-HTP) 100%
• Selective Incorporation 100%
• Oxalate Decarboxylase 100%
• Long-range Electron Transfer 100%
• Active Sites 40%
• Mn(III) 40%
• Proton 20%
• Carbon Dioxide 20%
• Hydroxyl 20%
• Catalytic Efficiency 20%
• Enzymatic Activity 20%
• Bacillus Subtilis (B. subtilis) 20%
• Catalytic Mechanism 20%
• Monoanion 20%
• Oxalic Acid 20%
• Unnatural Amino Acids 20%
• Formate 20%
• Electron Transfer 20%
• Redox Protein 20%
• EPR Signal 20%
• Binuclear 20%
• Unimolecular 20%
• Acid Stress Response 20%
• Mn Ions 20%
• Hole Hopping 20%
• Tryptophan Dimers 20%
• Lower Boundary 20%
• Unnatural Amino Acid Incorporation 20%
• Hydrogen Electrode 20%
• Normal Hydrogen 20%
• Redox-neutral 20%
• Neutral Radical 20%
• Mn(II) 20%
• Standard Reduction Potential 20%
• Disproportionation Reaction 20%

Chemistry

• Oxalic Acid 100%
• Electron Transport 100%
• 5-Hydroxytryptophan 100%
• Amino Acid 40%
• Monomer 20%
• Hydrogen 20%
• Monoanion 20%
• Energetics 20%
• EPR Spectroscopy 20%
• Hydroxyl 20%
• Enzyme Activity 20%
• Disproportionation 20%
• Reduction Potential 20%
• Formate 20%
• formation 20%
• electrode 20%
• dimer 20%
• Tryptophan 20%
• Carbon Dioxide 20%

Biochemistry, Genetics and Molecular Biology

• Carboxy-Lyases 100%
• Electron Transport 100%
• Active Site 50%
• Enzyme 25%
• Amino Acids 25%
• Energy Transfer 25%
• N-Terminus 25%
• Catalytic Efficiency 25%
• Enzyme Activity 25%
• Bacillus Subtilis 25%
• Amino Acid Metabolism 25%
• Catalytic Mechanism 25%
• Disproportionation 25%
• Acidity 25%
• Tryptophan 25%