Synthesis and crystal structure of α-(3-phenylureido)-α-(2,4-dichloroptienyl) methyl phenylphosphinic acid

Jia Zhou, Ru Yu Chen, Hong Gen Wang, Xin Kan Yao

Research output: Contribution to journalArticle

Abstract

The crystal structure of α-(3-phenylureido)-α-(2,4-dichlorophenyl) methyl phenylphosphinic acid, C 20H 17Cl 2N 2O 3P, M r= 435. 25,which was obtained by desulphurisation of cis-3,4-diphenyl-5-(2,4-dichlorophenyl)-1,3,4-diazaphospholidin-2-thione-4-oxide utilizing Ag + - H 2O system in a yield of 89%, is reported. It crystallizes in orthorhombic space group Pca2 1 with a=11. 286(2), b=20. 601(4), c=8. 695 (2) Å, V=2021(1) Å 3, Z=4, D x=1. 430 g/cm 3, μ=4. 21 cm -1, F(000)=896. The final R factor is 0. 040 and R w, is 0. 045 for 946 unique observed reflections[I≥3σ (I)]. The result of X-ray analysis indicates that the molecules in the crystal are linked together by the O(3)⋯H(2d) - N(2d) intermolecular hydrogen-bondings.

Original languageEnglish
Pages (from-to)207-210
Number of pages4
JournalJiegou Huaxue
Volume16
Issue number3
StatePublished - 1997
Externally publishedYes

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Thiones
R Factors
X ray analysis
Oxides
Hydrogen bonds
Crystal structure
Crystals
acids
crystal structure
Molecules
oxides
hydrogen
synthesis
crystals
molecules
x rays
phenylphosphinic acid
diphenyl

Keywords

  • 1,3,4-diazaphospholidin-2-thione
  • Crystal structure
  • Desulphurisation reaction
  • Phosphinic acid derivative

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Condensed Matter Physics

Cite this

Synthesis and crystal structure of α-(3-phenylureido)-α-(2,4-dichloroptienyl) methyl phenylphosphinic acid. / Zhou, Jia; Chen, Ru Yu; Wang, Hong Gen; Yao, Xin Kan.

In: Jiegou Huaxue, Vol. 16, No. 3, 1997, p. 207-210.

Research output: Contribution to journalArticle

Zhou, Jia ; Chen, Ru Yu ; Wang, Hong Gen ; Yao, Xin Kan. / Synthesis and crystal structure of α-(3-phenylureido)-α-(2,4-dichloroptienyl) methyl phenylphosphinic acid. In: Jiegou Huaxue. 1997 ; Vol. 16, No. 3. pp. 207-210.
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AU - Yao, Xin Kan

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N2 - The crystal structure of α-(3-phenylureido)-α-(2,4-dichlorophenyl) methyl phenylphosphinic acid, C 20H 17Cl 2N 2O 3P, M r= 435. 25,which was obtained by desulphurisation of cis-3,4-diphenyl-5-(2,4-dichlorophenyl)-1,3,4-diazaphospholidin-2-thione-4-oxide utilizing Ag + - H 2O system in a yield of 89%, is reported. It crystallizes in orthorhombic space group Pca2 1 with a=11. 286(2), b=20. 601(4), c=8. 695 (2) Å, V=2021(1) Å 3, Z=4, D x=1. 430 g/cm 3, μ=4. 21 cm -1, F(000)=896. The final R factor is 0. 040 and R w, is 0. 045 for 946 unique observed reflections[I≥3σ (I)]. The result of X-ray analysis indicates that the molecules in the crystal are linked together by the O(3)⋯H(2d) - N(2d) intermolecular hydrogen-bondings.

AB - The crystal structure of α-(3-phenylureido)-α-(2,4-dichlorophenyl) methyl phenylphosphinic acid, C 20H 17Cl 2N 2O 3P, M r= 435. 25,which was obtained by desulphurisation of cis-3,4-diphenyl-5-(2,4-dichlorophenyl)-1,3,4-diazaphospholidin-2-thione-4-oxide utilizing Ag + - H 2O system in a yield of 89%, is reported. It crystallizes in orthorhombic space group Pca2 1 with a=11. 286(2), b=20. 601(4), c=8. 695 (2) Å, V=2021(1) Å 3, Z=4, D x=1. 430 g/cm 3, μ=4. 21 cm -1, F(000)=896. The final R factor is 0. 040 and R w, is 0. 045 for 946 unique observed reflections[I≥3σ (I)]. The result of X-ray analysis indicates that the molecules in the crystal are linked together by the O(3)⋯H(2d) - N(2d) intermolecular hydrogen-bondings.

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