Synthesis and Crystal Structure of 1-(o-methylphenyl)-2- (p-methoxyphenyl)-1,3,2-diazaphospholidin-4-thione-2-sulfide

Liang Nian He, Ru Yu Chen, Jia Zhou, Wang Hong-Gen, Yao Xin-Kan

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The crystal structure of the title compound C 16H 17N 2OPS 2, has been determined by single-crystal X-ray diffraction at 299K. The crystal is monoclinic with space group P2 1/n, a=9.549(2), b=7.954(5), c=23.039(8) Å, β=96.30(2)°, V=1739(2) A° 3, Z=4, M,=348.3, F(000)=728, μ(MoKα)=0.386 mm -1, D c= 1.331 g/cm 3. The final R factor is 0.044 and R w is 0.047 for 1002 observed reflections [I≥3σ(I)]. The five-membered heterocycle has a coplanar structure. The P-N(1) bond length (1.636 Å) indicates the existence of the d-p π bond between P and N(1) atoms of the title compound.

Original languageEnglish (US)
Pages (from-to)215-218
Number of pages4
JournalJiegou Huaxue
Volume16
Issue number3
StatePublished - 1997
Externally publishedYes

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Thiones
R Factors
Bond length
Sulfides
sulfides
Crystal structure
Single crystals
X ray diffraction
Atoms
Crystals
crystal structure
single crystals
synthesis
diffraction
crystals
atoms
x rays

Keywords

  • Crystal structure
  • Herbicidal activity
  • Lawesson's reagent
  • Phosphorus heterocycle

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Condensed Matter Physics

Cite this

Synthesis and Crystal Structure of 1-(o-methylphenyl)-2- (p-methoxyphenyl)-1,3,2-diazaphospholidin-4-thione-2-sulfide. / He, Liang Nian; Chen, Ru Yu; Zhou, Jia; Hong-Gen, Wang; Xin-Kan, Yao.

In: Jiegou Huaxue, Vol. 16, No. 3, 1997, p. 215-218.

Research output: Contribution to journalArticle

He, Liang Nian ; Chen, Ru Yu ; Zhou, Jia ; Hong-Gen, Wang ; Xin-Kan, Yao. / Synthesis and Crystal Structure of 1-(o-methylphenyl)-2- (p-methoxyphenyl)-1,3,2-diazaphospholidin-4-thione-2-sulfide. In: Jiegou Huaxue. 1997 ; Vol. 16, No. 3. pp. 215-218.
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abstract = "The crystal structure of the title compound C 16H 17N 2OPS 2, has been determined by single-crystal X-ray diffraction at 299K. The crystal is monoclinic with space group P2 1/n, a=9.549(2), b=7.954(5), c=23.039(8) {\AA}, β=96.30(2)°, V=1739(2) A° 3, Z=4, M,=348.3, F(000)=728, μ(MoKα)=0.386 mm -1, D c= 1.331 g/cm 3. The final R factor is 0.044 and R w is 0.047 for 1002 observed reflections [I≥3σ(I)]. The five-membered heterocycle has a coplanar structure. The P-N(1) bond length (1.636 {\AA}) indicates the existence of the d-p π bond between P and N(1) atoms of the title compound.",
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AU - Chen, Ru Yu

AU - Zhou, Jia

AU - Hong-Gen, Wang

AU - Xin-Kan, Yao

PY - 1997

Y1 - 1997

N2 - The crystal structure of the title compound C 16H 17N 2OPS 2, has been determined by single-crystal X-ray diffraction at 299K. The crystal is monoclinic with space group P2 1/n, a=9.549(2), b=7.954(5), c=23.039(8) Å, β=96.30(2)°, V=1739(2) A° 3, Z=4, M,=348.3, F(000)=728, μ(MoKα)=0.386 mm -1, D c= 1.331 g/cm 3. The final R factor is 0.044 and R w is 0.047 for 1002 observed reflections [I≥3σ(I)]. The five-membered heterocycle has a coplanar structure. The P-N(1) bond length (1.636 Å) indicates the existence of the d-p π bond between P and N(1) atoms of the title compound.

AB - The crystal structure of the title compound C 16H 17N 2OPS 2, has been determined by single-crystal X-ray diffraction at 299K. The crystal is monoclinic with space group P2 1/n, a=9.549(2), b=7.954(5), c=23.039(8) Å, β=96.30(2)°, V=1739(2) A° 3, Z=4, M,=348.3, F(000)=728, μ(MoKα)=0.386 mm -1, D c= 1.331 g/cm 3. The final R factor is 0.044 and R w is 0.047 for 1002 observed reflections [I≥3σ(I)]. The five-membered heterocycle has a coplanar structure. The P-N(1) bond length (1.636 Å) indicates the existence of the d-p π bond between P and N(1) atoms of the title compound.

KW - Crystal structure

KW - Herbicidal activity

KW - Lawesson's reagent

KW - Phosphorus heterocycle

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