Synthesis of Monofluoromethylarenes: Direct Monofluoromethylation of Diaryliodonium Bromides using Fluorobis(phenylsulfonyl)methane (FBSM)

Keyphrases

• Bromide 100%
• Methane 100%
• Monofluoroalkylation 100%
• Phenylsulfonyl 100%
• Diaryliodonium 100%
• Counterion 50%
• Controlled Experiment 50%
• Reaction Mechanism 50%
• Excellent Yields 50%
• Metal-mediated 50%
• Reaction Yield 50%
• Functional Group Tolerance 50%
• Linear Free Energy Relationships 50%
• Diaryliodonium Salts 50%
• SNAr 50%
• Hammett 50%
• Iodonium 50%
• Free Energy Analysis 50%
• Ionic Nature 50%
• Metal-free Protocol 50%

Chemistry

• Methane 100%
• Free Energy 50%
• Iodonium 50%
• Reaction Yield 50%