Theory of the chemical bond. V. Bond polarities of posttransition hydrides

Robert L. Matcha, Stephen C. King, Bernard Pettitt

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.

Original languageEnglish (US)
Pages (from-to)3944-3946
Number of pages3
JournalThe Journal of Chemical Physics
Volume73
Issue number8
StatePublished - 1980
Externally publishedYes

Fingerprint

Chemical bonds
chemical bonds
Hydrides
hydrides
polarity
Alkali halides
Perturbation techniques
Dipole moment
Charge transfer
alkali halides
dipole moments
derivation
charge transfer
perturbation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Theory of the chemical bond. V. Bond polarities of posttransition hydrides. / Matcha, Robert L.; King, Stephen C.; Pettitt, Bernard.

In: The Journal of Chemical Physics, Vol. 73, No. 8, 1980, p. 3944-3946.

Research output: Contribution to journalArticle

Matcha, Robert L. ; King, Stephen C. ; Pettitt, Bernard. / Theory of the chemical bond. V. Bond polarities of posttransition hydrides. In: The Journal of Chemical Physics. 1980 ; Vol. 73, No. 8. pp. 3944-3946.
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