Theory of the chemical bond. V. Bond polarities of posttransition hydrides

Robert L. Matcha; Stephen C. King; B. M. Pettitt

doi:10.1063/1.440580

Theory of the chemical bond. V. Bond polarities of posttransition hydrides

Robert L. Matcha
, Stephen C. King
, B. M. Pettitt

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.

Original language	English (US)
Pages (from-to)	3944-3946
Number of pages	3
Journal	The Journal of chemical physics
Volume	73
Issue number	8
DOIs	https://doi.org/10.1063/1.440580
State	Published - 1980
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.440580

Cite this

@article{e5a2007c83ea4076aad13d3f52530a64,

title = "Theory of the chemical bond. V. Bond polarities of posttransition hydrides",

abstract = "A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.",

author = "Matcha, \{Robert L.\} and King, \{Stephen C.\} and Pettitt, \{B. M.\}",

year = "1980",

doi = "10.1063/1.440580",

language = "English (US)",

volume = "73",

pages = "3944--3946",

journal = "The Journal of chemical physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "8",

}

TY - JOUR

T1 - Theory of the chemical bond. V. Bond polarities of posttransition hydrides

AU - Matcha, Robert L.

AU - King, Stephen C.

AU - Pettitt, B. M.

PY - 1980

Y1 - 1980

N2 - A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.

AB - A classical derivation of a dipole moment model derived earlier by a quantum mechanical implicit perturbation technique is given. This model is used to determine the bond polarities of the posttransition (Groups IIIA-VIIA) hydrides. The polarity measures the extent of charge transfer in a bond. Polarities of alkali halides and posttransition hydrides are used to illustrate the gradual change in bond polarities with nuclear charge across the periodic table.

UR - https://www.scopus.com/pages/publications/36749118459

UR - https://www.scopus.com/pages/publications/36749118459#tab=citedBy

U2 - 10.1063/1.440580

DO - 10.1063/1.440580

M3 - Article

AN - SCOPUS:36749118459

SN - 0021-9606

VL - 73

SP - 3944

EP - 3946

JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 8

ER -

Theory of the chemical bond. V. Bond polarities of posttransition hydrides

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this